A Laboratory Investigation of the Effect of Temperature on Densities and Viscosities of Un-conventional Fuel (Residual Fuel Oil) and Petroleum Diesel Oil.

Authors

  • Maduka Augustine Nwufo Federal Polytechnic Oko Anambra State Nigeria

DOI:

https://doi.org/10.26740/vubeta.v3i1.42708

Keywords:

Residual Fuel Oil, Viscosity, Temperature Effects, Density, Fuel Characterization

Abstract

Fuel properties such as viscosity and density play a critical role in determining the efficiency, performance, and environmental footprint of combustion systems, particularly in industrial and power generation applications. Understanding how these properties respond to temperature variations is essential for optimizing fuel handling, atomization, and combustion, especially when considering the use of unconventional fuels such as Residual Fuel Oil (RFO). This study investigated the effect of temperature on the viscosity and density of RFO compared with conventional petroleum diesel. Fuel samples were analyzed in a controlled laboratory environment using a digital rotational viscometer and ASTM-compliant hydrometer across a temperature range of 20°C to 100°C, at 10°C intervals. Measurements were replicated and subjected to regression modeling. The results revealed that both viscosity and density decrease as temperature increases, with viscosity exhibiting an exponential decline and density showing a nearly linear trend. RFO demonstrated significantly higher viscosity than diesel at all temperatures, indicating the necessity of preheating for proper flow and combustion. Statistical analysis confirmed the differences in thermal behavior were significant. These findings have important implications for energy systems considering fuel switching or dual-fuel operations, as they highlight the need for thermal management strategies when using heavier fuels like RFO. The study contributes valuable data for the design and operation of systems that aim to integrate unconventional fuels into existing diesel infrastructure while maintaining efficiency and compliance with emission standards.

References

[1] I. Ahmed, M. Khan, H. Abulkhair, A. Shaiban, H. Organji, & A. Alsaiari, "Influence of Hydrogenated Diesel/H2O2 Blend Fuel on Diesel Engine Performance and Exhaust Emission Characterization", Scientific Reports, vol. 13, no. 1, 2023. https://doi.org/10.1038/s41598-023-27569-5

[2] S. d’Ambrosio, A. Mancarella, & O. Marello, "Characterization of Hydrotreated Vegetable Oil (HYO) in a Euro 6 Diesel Engine as a Drop-in Fuel and With a Dedicated Calibration", Journal of Physics: Conference Series, vol. 2648, no. 1, pp. 012074, 2023. https://doi.org/10.1088/1742-6596/2648/1/012074

[3] A. Diané, Y. Gounkaou, S. Zongo, T. Daho, & H. Jeanmart, "Characterization, at Partial Loads, of the Combustion and Emissions of a Dual-Fuel Engine Burning Diesel and a Lean Gas Surrogate", Energies, vol. 16, no. 15, pp. 5587, 2023. https://doi.org/10.3390/en16155587

[4] A. Wulandari, N. Rossiana, F. Zahdi, R. Nuraulia et al., "Formulation and Characterization of Bio-Briquettes and Bio-Pellets from Ramie (Boehmeria nivea) Biomass as Renewable Fuel", Sustainability, vol. 16, no. 24, pp. 10930, 2024. https://doi.org/10.3390/su162410930

[5] I. Matasyoh, B. Osodo, J. Muguthu, & E. Kombe, "Characterization, Performance Evaluation and Optimization of Wheat Straw – Bagasse Blended Fuel Pellets", International Journal of Renewable Energy Development, vol. 13, no. 3, pp. 457-465, 2024. https://doi.org/10.61435/ijred.2024.58098

[6] B. Sun, S. Zhao, Y. Zhai, Q. Liu, G. Wu, & H. Wu, "Effect of Fuel Physicochemical Properties on Spray and Particulate Emissions", ACS Omega, vol. 7, no. 48, pp. 44251-44265, 2022. https://doi.org/10.1021/acsomega.2c05747

[7] N. Hamidi, I. Ibadurrohman, L. Yuliati, W. Winarto, & D. Darmadi, "The Effect of Alcohol Compounds on Droplet Combustion Characteristics of Unsaturated Fatty Acid of Linoleic Acid", Trends in Sciences, vol. 20, no. 7, pp. 6720, 2023. https://doi.org/10.48048/tis.2023.6720

[8] A. Ferrari and A. Vassallo, "The Impact of the Common Rail Fuel Injection System on Performance and Emissions of Modern and Future Compression Ignition Engines", Energies, vol. 18, no. 19, pp. 5259, 2025. https://doi.org/10.3390/en18195259

[9] J. Hunicz, J. Matijošius, A. Rimkus, A. Kilikevičius, P. Kordos, & M. Mikulski, "Efficient Hydrotreated Vegetable Oil Combustion Under Partially Premixed Conditions with Heavy Exhaust Gas Recirculation", Fuel, vol. 268, pp. 117350, 2020. https://doi.org/10.1016/j.fuel.2020.117350

[10] H. Zhang, Z. Bi, P. Sun, A. Chen, T. Wågberg, X. Hu et al., "Dense Crystalline/Amorphous Phosphides/Oxides Interfacial Sites for Enhanced Industrial-Level Large Current Density Seawater Oxidation", ACS Nano, vol. 17, no. 16, pp. 16008-16019, 2023. https://doi.org/10.1021/acsnano.3c04519

[11] C. Tsai, Y. Shen, & W. Tsai, "Thermochemical Characterization of Rice-Derived Residues for Fuel Use and Its Potential for Slagging Tendency", Fire, vol. 6, no. 6, pp. 230, 2023. https://doi.org/10.3390/fire6060230

[12] J. Churchill, G. Rath, V. Borugadda, & A. Dalai, "Fractionation and Catalytic Upgradation of Crude Tall Oil into Sustainable Transportation Fuels via Blending and Co-Refining", Sustainable Energy & Fuels, vol. 9, no. 18, pp. 4989-5003, 2025. https://doi.org/10.1039/d5se00561b

[13] I. Kolev, D. Stratiev, I. Shishkova, K. Atanassov, S. Ribagin, S. Sotirov et al., "Effect of Crude Oil Quality on Properties of Hydrocracked Vacuum Residue and Its Blends with Cutter Stocks to Produce Fuel Oil", Processes, vol. 11, no. 6, pp. 1733, 2023. https://doi.org/10.3390/pr11061733

[14] M. Fadzil, S. Abdul-Razak, A. Razali, M. Salleh, & H. Zabiri, "Calculation of the Viscosity of a Mixture of Heavy Hydrocarbon Oil with Temperature Relation Consideration", ACS Omega, vol. 10, no. 29, pp. 31274-31297, 2025. https://doi.org/10.1021/acsomega.4c06517

[15] D. Stratiev, I. Shiskova, V. Toteva, G. Georgiev, R. Dinkov, I. Kolev et al., "Experience in Processing Alternative Crude Oils to Replace Design Oil in the Refinery", Resources, vol. 13, no. 6, pp. 86, 2024. https://doi.org/10.3390/resources13060086

[16] X. Li, Q. Liu, Y. Ma, G. Wu, Y. Zhou, & Q. Fu, "Simulation Study on the Combustion and Emissions of a Diesel Engine with Different Oxygenated Blended Fuels", Sustainability, vol. 16, no. 2, pp. 631, 2024. https://doi.org/10.3390/su16020631

[17] N. Sánchez, C. Halmenschlager, & A. Klerk, "Viscosity–Temperature Relationship and Binary Viscosity Mixing Rules for Fast Pyrolysis and Hydrothermal Liquefaction Oil Blends", Energy & Fuels, vol. 36, no. 18, pp. 10990-11000, 2022. https://doi.org/10.1021/acs.energyfuels.2c01824

[18] D. Graf, P. Neuner, & R. Rauch, "Standard-Compliant Gasoline by Upgrading a DTG-Based Fuel through Hydroprocessing the Heavy-Ends and Blending of Oxygenates", Fuels, vol. 4, no. 2, pp. 156-173, 2023. https://doi.org/10.3390/fuels4020010

[19] L. Jung, A. Mages, & A. Sauer, "Numerical Investigation and Simulation of Hydrogen Blending into Natural Gas Combustion", Energies, vol. 17, no. 15, pp. 3819, 2024. https://doi.org/10.3390/en17153819

[20] H. Mohammadhosseini and J. Yatim, "Microstructure and Residual Properties of Green Concrete Composites Incorporating Waste Carpet Fibers and Palm Oil Fuel Ash at Elevated Temperatures", Journal of Cleaner Production, vol. 414, pp. 137728, 2023. https://doi.org/10.1016/j.jclepro.2023.137728

[21] M. Alabbad, R. Gautam, E. Guevara, S. Saxena, E. Barradah, O. Chatakonda et al., "TG-DSC and TG-FTIR Analysis of Heavy Fuel Oil and Vacuum Residual Oil Pyrolysis and Combustion: Characterization, Kinetics, and Evolved Gas Analysis", Journal of Thermal Analysis and Calorimetry, vol. 148, no. 5, pp. 1875-1898, 2023. https://doi.org/10.1007/s10973-022-11871-x

[22] P. Krishnapriya, U. Salini, & S. Pushpan, "Performance Evaluation of Palm Oil Fuel Ash for Residual Soil Stabilization", Lecture Notes in Civil Engineering, pp. 643-654, 2024. https://doi.org/10.1007/978-981-97-4852-5_52

[23] N. Narudin, H. Abdullah, K. Razak, M. Taib, & B. Hadi, "Application of Granitic Residual Soil and Palm Oil Fuel Ash as an Absorbing Material to Develop High-Strength Anti-microwave Brick Walls", Lecture Notes in Electrical Engineering, pp. 373-384, 2024. https://doi.org/10.1007/978-981-97-3847-2_32

[24] S. Shriiraam, S. N., & S. Suruthi, "Residual Fuel Oil Dump Detection Buoy: A Novel Approach to Monitor Illegal Oil Dumping in Oceans", 2024 10th International Conference on Advanced Computing and Communication Systems (ICACCS), p. 816-821, 2024. https://doi.org/10.1109/icaccs60874.2024.10717283

[25] I. Zahariev and A. Atanasov, "Reasons for not Using the Energy Potential of Residual Biomass Generated During the Contour Pruning of Oil-Bearing Roses as Heating Fuel", Lecture Notes in Civil Engineering, pp. 477-487, 2024. https://doi.org/10.1007/978-3-031-70955-5_52

[26] Z. Li, M. Wang, N. Li, D. Gu, C. Yan, D. Yuan et al., "Solar Oil Refinery: Solar-Driven Hybrid Chemical Cracking of Residual Oil Towards Efficiently Upgrading Fuel and Abundantly Generating Hydrogen", Energy Conversion and Management, vol. 300, pp. 117900, 2024. https://doi.org/10.1016/j.enconman.2023.117900

[27] K. Kuzmin, R. Sultanbekov, С. Хромова, M. Vovk, & V. Rudko, "Establishing the Influence of Recycled Used Oil on the Sedimentation Stability of Residual Marine Fuel", Fuel, vol. 389, pp. 134625, 2025. https://doi.org/10.1016/j.fuel.2025.134625

[28] L. Abdulkareem, M. Mustafa, K. Ahmed, & S. Simo, "Evaluating High-Sulfur Residuals from Iraqi Crude Oils as a Potential Fuel Source for Heavy Industries", Iranian Journal of Chemistry & Chemical Engineeering, vol. 44, no. 03, pp. 909-916, 2025. https://doi.org/10.30492/ijcce.2024.2041630.6807

[29] P. Kasar, L. Songachan, & M. Ahmaruzzaman, "Liquid Products from Ternary, Quaternary, and Quinary Co-Pyrolysis of Waste Plastics and Residual Fuel Oil: Characterization and Potential Applications", Journal of Inorganic and Organometallic Polymers and Materials, vol. 35, no. 3, pp. 1640-1661, 2024. https://doi.org/10.1007/s10904-024-03393-w

[30] S. Said, M. Hassan, & S. Mikhail, "Orange Peel Derived Biochar Activated Thermochemically by H3PO4 to Serve as an Efficient Demetallization Adsorbent for Nickel and Vanadyl Tetraphenyl Porphyrins from Egyptian Residual Fuel Oil: Kinetic and Isotherm Studies", Diamond and Related Materials, vol. 159, pp. 112805, 2025. https://doi.org/10.1016/j.diamond.2025.112805

[31] E. Boom-Cárcamo, R. Peñabaena‐Niebles, & J. Alean, "Scenario Analysis of the Use of Oil Palm Residual Biomass for Bioenergy Generation: A Comparison with Fossil Fuels", Energy, vol. 335, pp. 137933, 2025. https://doi.org/10.1016/j.energy.2025.137933

[32] N. Yao, L. Yu, Z. Fu, X. Shen, T. Hou, X. Li uet al., "Probing the Origin of Viscosity of Liquid Electrolytes for Lithium Batteries", Angewandte Chemie International Edition, vol. 62, no. 41, 2023. https://doi.org/10.1002/anie.202305331

[33] X. Zhang, J. Xu, L. Zhai, & W. Zhao, "Characterization of Aerosol Properties from the Burning Emissions of Typical Residential Fuels on the Tibetan Plateau", Environmental Science & Technology, vol. 56, no. 20, pp. 14296-14305, 2022. https://doi.org/10.1021/acs.est.2c04211

[34] E. Ahmed, A. Farghali, & M. Hmamm, "Development of Cu-MOF@PVDF-PS Hybrid Membranes for High-Temperature Proton Exchange Membranes: Electrospinning, Characterization, and Fuel Cell Performance", RSC Advances, vol. 15, no. 36, pp. 29777-29798, 2025. https://doi.org/10.1039/d5ra03667d

[35] P. Kasar and M. Ahmaruzzaman, "Characterization of Liquid Products Obtained from Catalytic Binary Co-Cracking of Residual Fuel Oil with Various Waste Plastics", Scientific Reports, vol. 12, no. 1, pp. 10987, 2022. https://doi.org/10.1038/s41598-022-15371-8

[36] K. Ramalingam, S. Vellaiyan, P. Elumalai, S. Khan, Z. Mahmoud, & C. Saleel, "Challenges and Opportunities of Low Viscous Biofuel─A Prospective Review", ACS Omega, vol. 8, no. 19, pp. 16545-16560, 2023. https://doi.org/10.1021/acsomega.3c00387

[37] D. Stratiev, S. Nenov, I. Shishkova, S. Sotirov, E. Sotirova, R. Dinkov et al., "Prediction of Viscosity of Blends of Heavy Oils with Diluents by Empirical Correlations and Artificial Neural Network", Industrial & Engineering Chemistry Research, vol. 62, no. 49, pp. 21449-21463, 2023. https://doi.org/10.1021/acs.iecr.3c02472

[38] X. Wang, S. Liang, H. Wang, S. Huang, & B. Liao, "Do Fossil-Fuel Price Distortions Impact the Low-Carbon Transition in China’s Energy Intensive Industries?", Frontiers in Energy Research, vol. 9, 2022. https://doi.org/10.3389/fenrg.2021.805224

[39] V. Kornienko, M. Radchenko, A. Radchenko, H. Koshlak, & R. Radchenko, "Enhancing the Fuel Efficiency of Cogeneration Plants by Fuel Oil Afterburning in Exhaust Gas before Boilers", Energies, vol. 16, no. 18, pp. 6743, 2023. https://doi.org/10.3390/en16186743

[40] O. Chiavola, F. Palmieri, & F. Verdoliva, "Characteristics of High-Pressure Injection Pump Operated with Renewable Fuel for Diesel Engines", Energies, vol. 17, no. 7, pp. 1656, 2024. https://doi.org/10.3390/en17071656

Downloads

Published

2026-01-21

How to Cite

[1]
M. A. Nwufo, “A Laboratory Investigation of the Effect of Temperature on Densities and Viscosities of Un-conventional Fuel (Residual Fuel Oil) and Petroleum Diesel Oil”., Vokasi Unesa Bull. Eng. Technol. Appl. Sci., vol. 3, no. 1, pp. 55–63, Jan. 2026.
Abstract views: 0 , PDF Downloads: 0

Similar Articles

1 2 > >> 

You may also start an advanced similarity search for this article.