Silver Nanorods Layer Based on Polyvinyl Alcohol on Glass Substrates by Dip-Coating Method
DOI:
https://doi.org/10.26740/jpfa.v9n1.p1-9Keywords:
silver nanorods, transparent electrode, optical properties, sheet resistance, dip-coatingAbstract
This research reports the investigation of the performance of a thin layer based on silver nanorods using the dip-coating method. The synthesis was conducted by polyol method at an oil bath temperature of 140 °C. In the synthesis of silver nanorods, materials used were silver nitrate (AgNO3) as the main raw material, ethylene glycol (EG) as the solvent, and a small amount of sodium chloride (NaCl) as a mediated-agent (precursor). Polyvinyl alcohol (PVA) used as a capping agent and stabilizer in this process. Diameter and length of silver nanorods were 800 nm and 15 µm, respectively. Furthermore, the silver nanorods suspension was deposition onto a glass substrate with a variety of dipping cycles. The result showed the thickness of the thin layer is linear with a number of dipping cycles. Electrical and optical properties of thin layer show that sheet resistance about of 30 Ω sq-1 by transmittance above of 80%. The silver nanorods thin film can be used as a conductive and transparent electrode for various optoelectronic applications.
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Junaidi, Triyana K, Suharyadi E, Harsojo, and Wu LYL. The Roles of Polyvinyl Alcohol (PVA) as the Capping Agent on the Polyol Method for Synthesizing Silver Nanowires. Journal of Nano Research. 2017; 49: 174-180. DOI: https://doi.org/10.4028/www.scientific.net/JNanoR.49.174.
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Johan MR, Azri N, Aznan NAK, Yee ST, Ho IH, Ooi SW, Singho ND, and Aplop F. Synthesis and Growth Mechanism of Silver Nanowires Through Different Mediated Agents (CuCl2 and NaCl) Polyol Process. Journal of Nanomaterials. 2014; 105454. DOI: http://dx.doi.org/10.1155/2014/105454.
Yan Y, Chen K, Li H, Hong W, Hu X, and Xu Z. Capping Effect of Reducing Agents and Surfactants in Synthesizing Silver Nanoplates. Transactions of Nonferrous Metals Society of China. 2014; 24(11): 3732-3738. DOI: https://doi.org/10.1016/S1003-6326(14)63522-6.
Hu L, Kim HS, Lee JY, Peumans P, and Cui Y. Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire Electrodes. ACS Nano. 2010; 4(5): 2955-2963. DOI: https://doi.org/10.1021/nn1005232.
Junaidi, Aba L, and Triyana K. An Automatic Data Acquisition System for Optical Characterization of PEDOT : PSSbased Gas Sensor. AIP Conference Proceeding. 2015; 1656(1): 040001. DOI: https://doi.org/10.1063/1.4917108.
Junaidi, Triyana K, Harsojo, and Suharyadi E. 2017. High-Performance Silver Nanowire Film on Flexible Substrate Prepared by Meyer-rod Coating. IOP Conf. Series: Materials Science and Engineering. 2017; 202: 012055. DOI: http://dx.doi.org/10.1088/1757-899X/202/1/012055.
Kim H, Gilmore CM, Piqué A, Horwitz JS, Mattoussi H, Murata H, Kafafi ZH, and Chrisey DB. Electrical, Optical, and Structural Properties of IndiumTinOxide Thin Films for Organic Light-Emitting Devices. Journal of Applied Physics. 1999; 86(11): 6451-6461. DOI: https://doi.org/10.1063/1.371708.
Kim YS, Chang MH, Lee EJ, Ihm DW, and Kim JY. Improved Electrical Conductivity of PEDOT-Based Electrode Films Hybridized
with Silver Nanowires. Synthetic Metals. 2014; 195: 69-74. DOI: https://doi.org/10.1016/j.synthmet.2014.04.032.
Kim D, Zhu L, Jeong DJ, Chun K, Bang YY, Kim SR, Kim JH, and Oh SK. Transparent Flexible Heater Based on Hybrid of Carbon Nanotubes and Silver Nanowires. Carbon. 2013; 63: 530-536. DOI: https://doi.org/10.1016/j.carbon.2013.07.030.
Hecht DS, Thomas D, Hu L, Ladous C, Lam T, Park Y, Irvin G, and Drzaic P. Carbon-Nanotube Film on Plastic as Transparent Electrode for Resistive Touch Screens. Journal of the Society for Information Display. 2009; 17(11): 941-946. DOI: https://doi.org/10.1889/JSID17.11.941.
Teppei A, Jinting J, Masaya N, Hirotaka K, Shijo N, Tohru SKS, and Katsuaki S. Low Haze Transparent Electrodes and Highly Conducting Air Dried Films with Ultra-Long Silver Nanowires Synthesized by One-Step Polyol Method. Nano Research. 2014; 7(2): 236-245. DOI: https://doi.org/10.1007/s12274-013-0391-x.
Azuma K, Sakajiri K, Matsumoto H, Kang S, Watanabe J, and Tokita MF. Facile Fabrication of Transparent and Conductive
Nanowire Networks by Wet Chemical Etching With an Electrospun Nanofiber Mask Template. Materials Letter. 2014; 115: 187-189. DOI: https://doi.org/10.1016/j.matlet.2013.10.054.
Dinh DA, Hui KN, Hui KS, Kumar P, and Singh J. Silver Nanowires: A Promising Transparent Conducting Electrode Material for Optoelectronic and Electronic Applications. Reviews in Advanced Sciences and Engineering. 2013; 2(4): 1-22. DOI: http://dx.doi.org/10.1166/rase.2013.1048.
Feliciano J and MartÃnez-Iñesta MM. Synthesis and Characterization of Pd, Cu, and Ag Nanowires in Anodic Alumina Membranes Using Solid State Reduction. Materials Letter. 2012; 82(3): 211-213. DOI: https://doi.org/10.1016/j.matlet.2012.05.115.
Tang X, Tsuji M, Jiang P, Nishio M, Jang SM, and Yoon SH. Rapid and High-Yield Synthesis of Silver Nanowires Using Air-Assisted Polyol Method with Chloride Ions. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2009; 338(1-3): 33-39. DOI: https://doi.org/10.1016/j.colsurfa.2008.12.029.
Rajesh D and Sunandana CS. Controlled Formation of Porous Silver Nanowires. Chemical Physics Letters. 2014; 610-611: 363-368. DOI: https://doi.org/10.1016/j.cplett.2014.07.056.
Amirjani A, Marashi P, and Fatmehsari DH. Effect of AgNO3 Addition Rate on Aspect Ratio of CuCl2Mediated Synthesized Silver Nanowires Using Response Surface Methodology. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2014; 444: 33-39. DOI: https://doi.org/10.1016/j.colsurfa.2013.12.03.
Mi HY, Li Z, Turng LS, Sun Y, and Gong S. Silver Nanowire/Thermoplastic Polyurethane Elastomer Nanocomposites: Thermal, Mechanical, and Dielectric Properties. Materials Design. 2014; 56: 398-404. DOI: https://doi.org/10.1016/j.matdes.2013.11.029.
Tokuno T, Nogi M, Jiu J, and Suganuma K. Hybrid Transparent Electrodes of Silver Nanowires and Carbon Nanotubes: A Low-Temperature Solution Process. Nanoscale Research Letters. 2012; 7(1): 281. DOI: https://doi.org/10.1186/1556-276X-7-281.
Naito K, Yoshinaga N, Tsutsumi E, and Akasaka Y. Transparent Conducting Film Composed of Graphene and Silver Nanowire Stacked Layers. Synthetic Metals. 2013; 175: 42-46. DOI: https://doi.org/10.1016/j.synthmet.2013.04.025.
Margulis GY, Christoforo MG, Lam D, Beiley ZM, Bowring CDB, Salleo A, and McGehee MD. Spray Deposition of Silver Nanowire Electrodes for Semitransparent Solid-State Dye-Sensitized Solar Cells. Advanced Energy Materials. 2013; 3(12): 1657-1663. DOI: https://doi.org/10.1002/aenm.201300660.
Sachse C, Müller-Meskamp L, Bormann L, Kim YH, Lehnert F, Philipp A, Beyer B, and Leo K. Transparent, Dip-Coated Silver Nanowire Electrodes for Small Molecule Organic Solar Cells. Organic Electronics: Physics, Materials, Applications. 2013; 14(1): 143-148. DOI: https://doi.org/10.1016/j.orgel.2012.09.032.
Wu LYL, Kerk WT, and Wong CC. Transparent Conductive Fi Lm by Large Area Roll-To-Roll Processing. Thin Solid Films. 2013; 544: 427-432. DOI: https://doi.org/10.1016/j.tsf.2013.02.087.
Lim JW, Cho DY, Jihoon-Kim, Na SI, and Kim HK. Simple Brush-Painting of Flexible and Transparent Ag Nanowire Network Electrodes as an Alternative ITO Anode for Cost-Efficient Flexible Organic Solar Cells. Solar Energy Materials and Solar Cells. 2012; 107: 348-354. DOI: https://doi.org/10.1016/j.solmat.2012.07.012.
Liu CH and Yu X. Silver Nanowire-Based Transparent, Flexible, and Conductive Thin Film. Nanoscale Research Letters. 2011; 6(1): 75. DOI: https://doi.org/10.1186/1556-276X-6-75.
Junaidi, Triyana K, Sosiati H, Suharyadi E, and Harsoyo. Effect of Temperature on Silver Nanorods Synthesized by Polyol Method. Advanced Materials Research. 2015; 1123: 256-259. DOI: https://doi.org/10.4028/www.scientific.net/AMR.1123.256.
Junaidi, Triyana K, Suharyadi E, Harsojo, and Wu LYL. The Roles of Polyvinyl Alcohol (PVA) as the Capping Agent on the Polyol Method for Synthesizing Silver Nanowires. Journal of Nano Research. 2017; 49: 174-180. DOI: https://doi.org/10.4028/www.scientific.net/JNanoR.49.174.
Nghia NV, Truong NNK, Thong NM, and Hung NP. Synthesis of Nanowire-Shaped Silver by Polyol Process of Sodium Chloride. International Journal of Materials and Chemistry. 2012; 2(2): 75-78. DOI: https://doi.org/10.5923/j.ijmc.20120202.06.
Johan MR, Azri N, Aznan NAK, Yee ST, Ho IH, Ooi SW, Singho ND, and Aplop F. Synthesis and Growth Mechanism of Silver Nanowires Through Different Mediated Agents (CuCl2 and NaCl) Polyol Process. Journal of Nanomaterials. 2014; 105454. DOI: http://dx.doi.org/10.1155/2014/105454.
Yan Y, Chen K, Li H, Hong W, Hu X, and Xu Z. Capping Effect of Reducing Agents and Surfactants in Synthesizing Silver Nanoplates. Transactions of Nonferrous Metals Society of China. 2014; 24(11): 3732-3738. DOI: https://doi.org/10.1016/S1003-6326(14)63522-6.
Hu L, Kim HS, Lee JY, Peumans P, and Cui Y. Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire Electrodes. ACS Nano. 2010; 4(5): 2955-2963. DOI: https://doi.org/10.1021/nn1005232.
Junaidi, Aba L, and Triyana K. An Automatic Data Acquisition System for Optical Characterization of PEDOT : PSSbased Gas Sensor. AIP Conference Proceeding. 2015; 1656(1): 040001. DOI: https://doi.org/10.1063/1.4917108.
Junaidi, Triyana K, Harsojo, and Suharyadi E. 2017. High-Performance Silver Nanowire Film on Flexible Substrate Prepared by Meyer-rod Coating. IOP Conf. Series: Materials Science and Engineering. 2017; 202: 012055. DOI: http://dx.doi.org/10.1088/1757-899X/202/1/012055.
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2019-06-30
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Junaidi, J., Riyanto, A., Triyana, K. and Khairurrijal, K. (2019) “Silver Nanorods Layer Based on Polyvinyl Alcohol on Glass Substrates by Dip-Coating Method”, Jurnal Penelitian Fisika dan Aplikasinya (JPFA), 9(1), pp. 1–9. doi: 10.26740/jpfa.v9n1.p1-9.
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