A-Site Doped in Perovskite La(1-x)Bax/2Srx/2Mn0.4Ti0.6O3 (x = 0, 0.1, and 0.3) for Absorbing Microwave Material
DOI:
https://doi.org/10.26740/jpfa.v13n2.p106-118Keywords:
Microwave absorber, perovskite manganate, reflection loss, sol-gel methodAbstract
Microwave radiation can have harmful effects on our bodies. With increased exposure due to online activities, it is essential to use absorber materials like perovskite manganate to reduce radiation. In this study, perovskite manganate La(1-x)Bax/2Srx/2Mn0.4Ti0.6O3 (x = 0, 0.1, and 0.3) was synthesized using the sol-gel method. X-ray diffraction (XRD) analysis revealed that the two samples were multi-phased, LaMnO3 and La2Ti2O7, and were formed, exhibiting a rhombohedral crystal structure (R -3 c). Morphological characterization of the sample surface using a Scanning Electron Microscope (SEM) showed that as doping increases, the grain size decreases from 282.02 to 245.63 nm at x=0 and x=0.3, respectively. This result implies that doping leads to more uniform grain distribution and enhanced grain refinement. Characterization via Vibrating Sample Magnetometer (VSM) revealed that the maximum saturation value, 0.79 emu/g, was attained when x = 0. This sample exhibits soft magnetic properties, as evidenced by its coercivity (Hc) value of < 1kOe. Results from the Vector Network Analyzer (VNA) indicate that the absorption capacity of La(1-x)Bax/2Srx/2Mn0.4Ti0.6O3 increases, with a maximum reflection loss value of -25.5 dB with 1.5 mm thickness. Consequently, La(1-x)Bax/2Srx/2Mn0.4Ti0.6O3 demonstrates potential as a microwave absorber material.
References
Hu C, Zuo H, and Li Y. Effects of Radiofrequency Electromagnetic Radiation on Neurotransmitters in the Brain. Front Public Health. 2021; 9: 691880. DOI: https://doi.org/10.3389/fpubh.2021.691880.
Taryana Y, Manaf A, Sudrajat N, and Wahyu Y. Electromagnetic Wave Absorbing Materials on Radar Frequency Range. Jurnal Keramik dan Gelas Indonesia. 2019; 28(1): 1-28. DOI: https://doi.org/10.32537/jkgi.v28i1.5197.
Adi WA, Sarwanto Y, Taryana Y, and Soegijono B. Effects of The Geometry Factor on The Reflection Loss Characteristics of The Modified Lanthanum Manganite. Journal of Physics: Conference Series. 2018; 1091: 012028. DOI: https://doi.org/10.1088/1742-6596/1091/1/012028.
Lee YH and Mahendiran R. Transport and Electron Spin Resonance Studies in Mo-doped LaMnO3. AIP Advances. 2023; 13(2): 025115. DOI: https://doi.org/10.1063/9.0000442.
Autieri C, Cuoco M, Cuono G, Picozzi S, and Noce C. Orbital Order and Ferromagnetism in LaMn1?xGaxO3. Physica B Condens Matter. 2023; 648: 414407. DOI: https://doi.org/10.1016/j.physb.2022.414407.
Rizky F, Saptari SA, Tjahjono A, and Khaerudini DS. Perovskite Manganit Analysis Based on La0.7Ca0.3Mn1-xTixO3 (x=0, 0.1, 0.2, and 0.3) as Potential Microwave Absorber Material with Sol-Gel Method. Journal of Physics: Theories and Application. 2022; 6(1): 17-24. DOI: https://doi.org/10.20961/jphystheor-appl.v6i1.59142.
Behara S and Thomas T. Stability and Amphotericity Analysis in Rhombohedral ABO3 Perovskites. Materialia. 2020; 13: 100819. DOI: https://doi.org/10.1016/j.mtla.2020.100819.
Hanif SH bt M, Primus WC, and Sinin AE. Effect of Strontium Doping on Structural and Electrical Properties of LMTO Ceramic. AIP Conference Proceedinsgs. 2021; 2332(1): 040003. DOI: https://doi.org/10.1063/5.0042872.
Qu X-Y, Gou X-F, and Wang T-G. A Highly Accurate Interatomic Potential for LaMnO3 Perovskites with Temperature-Dependence of Structure and Thermal Properties. Computational Materials Science. 2021; 193: 110406. DOI: https://doi.org/10.1016/j.commatsci.2021.110406.
Hamdi R, Hayek SS, Samara A, Tong Y, Mansour SA, and Haik Y. Williamson-Hall Technique for Magnetic Cooling in Nanosized Manganite LaNi0.25Mn0.75O3 and Ferrite LaNi0.25Fe0.75O3. Solid State Sciences. 2023; 142: 107223. DOI: https://doi.org/10.1016/j.solidstatesciences.2023.107223.
Rueden CT, Schindelin J, Hiner MC, DeZonia BE, Walter AE, Arena ET, and Eliceiri KW. ImageJ2: ImageJ for The Next Generation of Scientific Image Data. BMC Bioinformatics. 2017; 18: 529. DOI: https://doi.org/10.1186/s12859-017-1934-z.
Orgiani P, Galdi A, Aruta C, Cataudella V, De Filippis G, Perroni CA, et al. Multiple Double-Exchange Mechanism by Mn2+ Doping in Manganite Compounds. Physics Review B. 2010; 82: 205122. DOI: https://doi.org/10.1103/PhysRevB.82.205122.
Amor N Ben, Bejar M, Dhahri E, Bekri M, Valente MA, and Hlil EK. Study of the Physical Properties of La2?xErxTi2O7(0 ? x ? 0.075) Compounds. The European Physical Journal Applied Physics. 2012; 59: 10601. DOI: https://doi.org/10.1051/epjap/2012120142.
Admi RI, Saptari SA, Tjahjono A, Rahman IN, and Adi WA. Synthesis and Characterization Microwave Absorber Properties of La0.7(Ca1-xSrx)0.3MnO3 Prepared by Sol-Gel Method. Journal of Physics: Conference Series. 2021; 1816: 012091. DOI: https://doi.org/10.1088/1742-6596/1816/1/012091.
Kumar D, Yadav RS, Monika, Singh AK, and Rai SB. Synthesis Techniques and Applications of Perovskite Materials. In Tian H. Perovskite Materials, Devices and Integration. London: IntechOpen; 2020. DOI: https://doi.org/10.5772/intechopen.86794.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2023 Jurnal Penelitian Fisika dan Aplikasinya (JPFA)

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Author(s) who wish to publish with this journal should agree to the following terms:
- Author(s) retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution-Non Commercial 4.0 License (CC BY-NC) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal for noncommercial purposes.
- Author(s) are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
The publisher publish and distribute the Article with the copyright notice to the JPFA with the article license CC-BY-NC 4.0.

