DOI: http://dx.doi.org/10.26740/jpfa.v8n1.p10-16

Elemental and Infrared Characterization of Contaminants in Second-Hand Cotton Garments From Flea Markets In Valencia City, Bukidnon, Philippines

Marilou Auxtero Pedroso Butanas, Bienvenido Masirin Butanas Jr.

Abstract


The use of Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy dispersive X-ray (EDX) characterizations have been indispensable techniques in distinguishing purity of the samples. These techniques give spectra that will be used to analyze the composition, morphology, purity, among others, of the material. One of its interesting applications is to assess elemental and chemical contaminations on second hand clothing. In this study, second hand (Ukay-Ukay) cotton garments from selected flea market sites in Valencia City, Bukidnon, Philippines were examined quantitatively for microbial and chemical contaminations by using FTIR, SEM, and EDX. The FTIR results obtained in both sites showed broad peaks at ~3336 cm-1 attributed to OH functional group, and absorption peaks at 2901.30 cm-1 associated to C-H bond, 1159.70 cm-1, 1107.44 cm-1 and 1053.82 cm-1 attributed to the stretches of CO bond. All of them were characteristics of cotton material. We observed degradation of the cotton material on both sites evident in the decreasing intensity of OH stretching (at peaks around ~3334 cm -1 [site A] and ~3332 cm -1 [site B]) and C-O stretching (around ~1500-1700 cm-1). These were due to the presence of microorganisms such as fungi (e.g. Aspergillus species). The degradation was also observed in the SEM results. Furthermore, peaks related to carboxylate contaminants were observed in both sites around ~1600 – 1800 cm-1 that may be caused by the exposure of the cotton garments in hydrochloric acid (HCl). In general, the characterization results on both sites indicated traces of microorganisms and that the second-hand cotton clothes were contaminated by hazardous chemicals.


Keywords


infrared properties; second hand garments; Ukay-Ukay; chemical contaminants; cotton degradation

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References


Abueg LC. The Economics of Secondhand Retail Trade: An Analysis of the Market for Ukay-Ukay. Philippine Journal of Development. 2005; 32(1): 53-77. Available from: https://dirp4.pids.gov.ph/ris/pjd/pidspjd05-1ukay.pdf.

Fijan S and Turk SS. Hospital Textiles, Are They a Possible Vehicle for Healthcare-Associated Infections? International Journal of Environmental Research and Public Health. 2012; 9(9): 3330-3343. DOI: https://doi.org/10.3390/ijerph9093330.

Wiener-Well Y, Galuty M, Rudensky B, Schlesinger Y, Attias D, and Yinnon AM. Nursing and Physician Attire as Possible Source of Nosocomial Infections. American Journal of Infection Control. 2011; 39(7): 555-559. DOI: https://doi.org/10.1016/j.ajic.2010.12.016.

El-Shishtawy RM, Asiri AM, Abdelwahed NAM, and Al-Otaibi MM. In situ Production of Silver Nanoparticle on Cotton Fabric and Its Antimicrobial Evaluation. Cellulose. 2011; 18: 75-82. DOI: https://doi.org/10.1007/s10570-010-9455-1.

Callaghan I. Bacterial Contamination of Nurses’ Uniforms: A Study. Nursing Standard. 1998; 13(1): 37-42. DOI: https://doi.org/10.7748/ns1998.09.13.1.37.c2525.

South Australia Public Health Fact Sheet. Second Hand Goods: A Guide for Consumers. Website. Available from: http://www.helth.sa.gov.au./PEHS/PDF-fil0es/ph-fs-consumers-secondhand.pdf. [accessed January 2009].

Muthiani YM, Matiru VN, and Bii C. Potential Skin Pathogens on Second Hand Clothes and the Effectiveness of Disinfection Methods. Scientific Conference Proceedings. Jomo Kenyatta University of Agriculture and Technology. 2010; 144 – 162. Available from: http://journals.jkuat.ac.ke/index.php/jscp/article/view/688.

Liu N, Sun G, and Zhu J. Photo-induced Self-cleaning Functions on 2-Anthraquinone Carboxylic Acid Treated Cotton Fabrics. Journal of Materials Chemistry. 2011; 21: 15383-15390. DOI: https://doi.org/10.1039/C1JM12805A.

Samaniego LG and Elumba E. Microbial Flora in Ukay-Ukay from Flea Markets in Valencia City, Bukidnon. CMU Journal of Science. 2016; 20 (3): 32-53. Available from: http://www.cmu.herdin.ph/index.php/component/herdin/?view=research&cid=62255.

Scilab. Homepage of Scilab. Available from: http://scilab.com.

Chung C, Lee M, and Choe EK. Characterization of Cotton Fabric Scouring by FT-IR ATR Spectroscopy. Carbohydrate Polymers. 2004; 58(4): 417-420. DOI: https://doi.org/10.1016/j.carbpol.2004.08.005.

Himmelsbach DS, Akin DE, Kim J, and Hardin IR. Chemical Structural Investigation of the Cotton Fiber Base and Associated Seed Coat: Fourier-Transform Infrared Mapping and Histochemistry. Textile Research Journal. 2003; 73(4): 218-288. DOI: https://doi.org/10.1177/004051750307300401.

Li L, Frey M, and Browning KJ. Biodegradability Study on Cotton and Polyester Fabrics. Journal of Engineered and Fabrics. 2010; 5(4): 42-51. Available from: https://www.jeffjournal.org/papers/Volume5/5-4-6Frey.pdf.

Allen A, Foulk J, and Gamble G. Preliminary Fourier-Transform Infrared Spectroscopy Analysis of Cotton Trash. The Journal of Cotton Science. 2007; 11(1):68-74. Available from: https://pubag.nal.usda.gov/download/8608/PDF.

Blackwell J, Vasko PD, and Koening JL. Infrared and Raman Spectra of the Cellulose From the Cell Wall of Valonia Ventricosa. Journal of Applied Physics. 1970; 41(11): 4375-4379. DOI: https://doi.org/10.1063/1.1658470.

Fischer G, Braun S Thissen R, and Dott W. FT-IR Spectroscopy as a Tool for Rapid Identification and Intra-species Characterization of Airborne Filamentous Fungi. Journal of Microbiological Methods. 2006; 64(1): 63-77. DOI: https://doi.org/10.1016/j.mimet.2005.04.005.

Sugiyama J, Person J, and Chanzy H. Combined Infrared and Electron Diffraction Study of the Polymorphism of Native Cellulose. Macromolecules. 1991; 24(9): 2461-2466. DOI: https://doi.org/10.1021/ma00009a050.

Michell AJ. Second Derivative FTIR Spectra of Native Cellulose. Carbohydrate Research. 1990; 197: 53-60. DOI: https://doi.org/10.1016/0008-6215(90)84129-I.

Michell AJ. Second-Derivative FTIR Spectra of Native Celluloses From Valonia and Tunicin. Carbohydrate Research. 1993; 241: 47-54. DOI: https://doi.org/10.1016/0008-6215(93)80093-T.

Kokot S, Czarnik-Matusewicz B, and Ozaki Y. Two-Dimensional Correlation Spectroscopy and Principal Component Analysis Studies of Temperature-Dependent IR Spectra of Cotton-Cellulose. Biopolymers. 2002; 67: 456-469. DOI: https://doi.org/10.1002/bip.10163.



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