Potensi Pencairan Batubara Kalimantan Timur Sebagai Bahan Bakar Cair Berdasarkan Kajian Geokimia Organik Degradasi Fraksi Polar Batubara, Pit Kancil, Kalimantan Timur
DOI:
https://doi.org/10.26740/otopro.v13n1.p9-22Keywords:
Batubara, Biomarka, Kalimantan, Sangatta, , PolarAbstract
Karakteristik biomarka hidrokarbon batubara Pit Kancil, Sangatta, Kalimantan Timur dapat memberikan informasi mengenai sumber bahan organik, lingkungan pengendapan, proses diagenesis dan kematangan batubara. Sampel batubara diekstraksi dengan metode soklet untuk memisahkan senyawa biomarka dari matrik sampel. Ekstrak biomarka difraksinasi menggunakan metode kromatografi kolom, sehingga diperoleh fraksi polar untuk selanjutnya di degradasi dan diidentifikasi menggunakan kromatografi gas-spektrometri massa (KG-SM).
Analisa geokimia organik hidrokarbon hasil degradasi fraksi polar batubara pit Kancil, Sangatta, Kalimantan Timur diperoleh biomarka diantaranya n-alkana C11-C23, alkil naftalena dan biomarka alkil fenantrena. Hasil analisa biomarka menunjukkan bahwa masukan organik batubara berasal dari tumbuhan tingkat tinggi sub-devisi Gimnospermae pada zaman Miosen dan telah melewati proses diagenesis dengan tingkat kematangan batubara yang rendah. Berdasarkan analisa biomarka, dan korelasi terhadap produk pencairan batubara, maka batubara Pit Kancil, Sangatta, Kalimantan Timur berpotensi untuk dicairkan pada proses pemanfaatannya sebagai bahan bakar kerosine dan solar.
References
Anggayana, K., (1996). Mikroskopische und organisch-geochemsiche Untersuchungen an Kohlen aus Indonesien ein Beitrag zur Genese und Fazies verschiedener Kohlenbecken. Dissertation. RWTH Aachen, Germany. p. 224.
Anyakora, C., dkk., 2005. GC/MS Analysis of Polynuclear Aromatic Hydrocarbons in Sediment Samples from The Niger Delta Region, Chemosphere, 60, 990-997.
Dev, S., 1989. Terpenoids. In: Rowe, J.W. (Ed.), Natural Products of Woody Plants I. Springer-Verlag, Berlin, pp. 691807.
Dutta, S., Mathews, P.R., Singh, B.D., Tripathi, S.M., Singh, A., Saraswati, P.K., Banerjee, S., Mann, U., (2011). Petrology, palynology and organic geochemistry of Eocene lignite of Matanomadh, Kutch Basin, western India: implications to depositional environment and hydrocarbon source potential. International Journal of Coal Geology 85, 91102.
Girriana, M., 2012, Percepatan Pembangunan Industri Gas Bumi, Badan Perencanaan Pembangunan Nasional, Laporan Akhir Kajian.
Hazai, I., Alexander, G., Essiger, B. & Szekely, T. (1988). Identification of aliphatic biological markers in brown coal. Fuel, 67, 897-904.
Horsfield, B., Yordy, K.L., dan Crelling, J.C., 1988. Determining the Petroleum Generating Potential of Coal Using Organic Geochemistry and Organic Petrology, Organic Geochemistry, 13, 121-129.
Kalkreuth, W., Keuser, C., Fowler, M., Li, M., McIntyre, D., Püttmann, W., Richardson, R., 1998. The petrology, organic geochemistry and palynology of Tertiary age Eureka Sound Group coals, Artic Canada. Organic Geochemistry 29, 799809.
Karlsson,O. The Composition of Peat Liquids : 2. Functional Group Analysis of Peat Liquefaction Products. Fuel. 1990; 69:613-16.
Legarreta, J.A., Arias, P.L., de Marco, I. Chemical and Petrograpic Characterization and Liquefaction Yield of Spanish Coals. Fuel Processing Technology. 1987 15:293-305.
Noble, R. A., Wu, C. H., Atkinson, C. D., (1991). Petroleum generation and migration from Talang Akar coals and shales offshore N.W. Java, Indonesia. Organic Geochemistry, 17, 363374.
Nugroho Hanan. Tinjauan terhadap Infrastruktur Transportasi Batubara Kalimantan. Jakarta: BAPPENAS, Edisi 03/th XI; 2006.
Peters, K. E & Moldowan, S. M. (1993). The biomarkers guide interprenting molecular fossil in petroleum and ancient sediment. Prentice Hall, Inc., New Jersey
Petrov, A., Vorobieva, N. S. & Zemskova, Z. K. (1985). Sterenes and triterpenes in brown coals, Org. Geochem., 8(4), 269-273
Prasad, M., 1993. Siwalik (Middle Miocene) woods from the Kalagarh area in the Himalayan foot hills and their bearing on palaeoclimate and phytogeography. Review of Paleobotany and Palynology 76, 4982.
Simoneit, B.R.T., Mazurek, M.A., 1982. Organic matter of the troposphere-II. Natural background of biogenic lipid matter in aerosols over the rural Western United States. Atmos. Environ. 16, 21392159.
Simoneit, R.B.T (1986), œDiterpenoid compound and other lipid in deep-see sediment and their geochemical significance, Geochimica at Chosmochimica Acta, 41, 463-476.
Singh, R. K., Alexander, R., dan Kagi, R. I., (1994), Identification and Occurence of Norcadalenes and Related Compounds In Crude Oils Sediments, Organic Geochemistry, 21, No.3/4, 249-256
Starchan, Michael, G., Alexander, R., dan Kagi, R.I., (1988), œA Comparison of selected biological marker compunds in some natural and synthetic liquid fuel. GPO Box U1987, Perth 6001, Western Australia.
Stefanova, M., Markovab, K., Marinova, S., Simoneit, B. R. T., (2005), œMolecular indicators for coal-forming vegetation of the Miocene Chukurovo lignite Bulgaria, Fuel, 84, 18301838.
Stefanova, M., Oros, D.R., Otto, A., Simoneit, B.R.T., 2002. Polar aromatic biomarkers in the Miocene Maritza-East lignite, Bulgaria. Organic Geochemistry 33, 10791091.
Sukandarrumidi. (1995). Batubara dan Gambut. Gadjah Mada University Press, Yogyakarta.
Sukandarrumidi. (1995). Batubara dan Gambut. Gadjah Mada University Press, Yogyakarta.
Tancell, P.J., Rhead, M.M., Pemberton, R.D., dan Braven, J., 1996. Diessel Combution of an Alkylated Polycyclic Aromatic Hydrocarbon, Fuel, 75, 717-723
Tuo, J., Wang, X., Chen, J., & Simoneit, B. R. T. (2003). Aliphatic And Diterpenoid Hydrocarbons And Their Individual Carbon Isotope Composition In Coals From Liaohe Basin, China. Organic Geochemistry, 34, 1615-1625.
van Aarssen, B. G. K., Hessels, J. K. C., Abbink, O. A., de Leeuw, J. W., (1992), œThe occurrence of polycyclic sesqui-, tri- and oligoterpenoid, derived from a resinsous polymeric cadinen in crude oil from Southeast Asia, Geochemica et cosmochimica Acta, 56, hal. 1231-1246
Wang, T. G. dan Simoneit, B. R. T., (1990), œOrganic geochemistry and coal petrology of tertiary brown coal in the Zhoujing mine, Baise basin, South China. II. Biomarker assemblage and significance, Fuel, 69, hal. 12-20
Widodo, S., Bechtel, A., Anggayana, K., dan Püttmann, W. (2009), Reconstruction of Floral Changes During Deposition of the Miocene Embalut Coal from Kutai Basin, Mahakam Delta, East Kalimantan, Indonesia by use of Aromatic Hydrocarbon Composition and Stable Carbon Isotope Ratios of Organic Matter, Organic Geochemistry, 40, 206218.
Anyakora, C., dkk., 2005. GC/MS Analysis of Polynuclear Aromatic Hydrocarbons in Sediment Samples from The Niger Delta Region, Chemosphere, 60, 990-997.
Dev, S., 1989. Terpenoids. In: Rowe, J.W. (Ed.), Natural Products of Woody Plants I. Springer-Verlag, Berlin, pp. 691807.
Dutta, S., Mathews, P.R., Singh, B.D., Tripathi, S.M., Singh, A., Saraswati, P.K., Banerjee, S., Mann, U., (2011). Petrology, palynology and organic geochemistry of Eocene lignite of Matanomadh, Kutch Basin, western India: implications to depositional environment and hydrocarbon source potential. International Journal of Coal Geology 85, 91102.
Girriana, M., 2012, Percepatan Pembangunan Industri Gas Bumi, Badan Perencanaan Pembangunan Nasional, Laporan Akhir Kajian.
Hazai, I., Alexander, G., Essiger, B. & Szekely, T. (1988). Identification of aliphatic biological markers in brown coal. Fuel, 67, 897-904.
Horsfield, B., Yordy, K.L., dan Crelling, J.C., 1988. Determining the Petroleum Generating Potential of Coal Using Organic Geochemistry and Organic Petrology, Organic Geochemistry, 13, 121-129.
Kalkreuth, W., Keuser, C., Fowler, M., Li, M., McIntyre, D., Püttmann, W., Richardson, R., 1998. The petrology, organic geochemistry and palynology of Tertiary age Eureka Sound Group coals, Artic Canada. Organic Geochemistry 29, 799809.
Karlsson,O. The Composition of Peat Liquids : 2. Functional Group Analysis of Peat Liquefaction Products. Fuel. 1990; 69:613-16.
Legarreta, J.A., Arias, P.L., de Marco, I. Chemical and Petrograpic Characterization and Liquefaction Yield of Spanish Coals. Fuel Processing Technology. 1987 15:293-305.
Noble, R. A., Wu, C. H., Atkinson, C. D., (1991). Petroleum generation and migration from Talang Akar coals and shales offshore N.W. Java, Indonesia. Organic Geochemistry, 17, 363374.
Nugroho Hanan. Tinjauan terhadap Infrastruktur Transportasi Batubara Kalimantan. Jakarta: BAPPENAS, Edisi 03/th XI; 2006.
Peters, K. E & Moldowan, S. M. (1993). The biomarkers guide interprenting molecular fossil in petroleum and ancient sediment. Prentice Hall, Inc., New Jersey
Petrov, A., Vorobieva, N. S. & Zemskova, Z. K. (1985). Sterenes and triterpenes in brown coals, Org. Geochem., 8(4), 269-273
Prasad, M., 1993. Siwalik (Middle Miocene) woods from the Kalagarh area in the Himalayan foot hills and their bearing on palaeoclimate and phytogeography. Review of Paleobotany and Palynology 76, 4982.
Simoneit, B.R.T., Mazurek, M.A., 1982. Organic matter of the troposphere-II. Natural background of biogenic lipid matter in aerosols over the rural Western United States. Atmos. Environ. 16, 21392159.
Simoneit, R.B.T (1986), œDiterpenoid compound and other lipid in deep-see sediment and their geochemical significance, Geochimica at Chosmochimica Acta, 41, 463-476.
Singh, R. K., Alexander, R., dan Kagi, R. I., (1994), Identification and Occurence of Norcadalenes and Related Compounds In Crude Oils Sediments, Organic Geochemistry, 21, No.3/4, 249-256
Starchan, Michael, G., Alexander, R., dan Kagi, R.I., (1988), œA Comparison of selected biological marker compunds in some natural and synthetic liquid fuel. GPO Box U1987, Perth 6001, Western Australia.
Stefanova, M., Markovab, K., Marinova, S., Simoneit, B. R. T., (2005), œMolecular indicators for coal-forming vegetation of the Miocene Chukurovo lignite Bulgaria, Fuel, 84, 18301838.
Stefanova, M., Oros, D.R., Otto, A., Simoneit, B.R.T., 2002. Polar aromatic biomarkers in the Miocene Maritza-East lignite, Bulgaria. Organic Geochemistry 33, 10791091.
Sukandarrumidi. (1995). Batubara dan Gambut. Gadjah Mada University Press, Yogyakarta.
Sukandarrumidi. (1995). Batubara dan Gambut. Gadjah Mada University Press, Yogyakarta.
Tancell, P.J., Rhead, M.M., Pemberton, R.D., dan Braven, J., 1996. Diessel Combution of an Alkylated Polycyclic Aromatic Hydrocarbon, Fuel, 75, 717-723
Tuo, J., Wang, X., Chen, J., & Simoneit, B. R. T. (2003). Aliphatic And Diterpenoid Hydrocarbons And Their Individual Carbon Isotope Composition In Coals From Liaohe Basin, China. Organic Geochemistry, 34, 1615-1625.
van Aarssen, B. G. K., Hessels, J. K. C., Abbink, O. A., de Leeuw, J. W., (1992), œThe occurrence of polycyclic sesqui-, tri- and oligoterpenoid, derived from a resinsous polymeric cadinen in crude oil from Southeast Asia, Geochemica et cosmochimica Acta, 56, hal. 1231-1246
Wang, T. G. dan Simoneit, B. R. T., (1990), œOrganic geochemistry and coal petrology of tertiary brown coal in the Zhoujing mine, Baise basin, South China. II. Biomarker assemblage and significance, Fuel, 69, hal. 12-20
Widodo, S., Bechtel, A., Anggayana, K., dan Püttmann, W. (2009), Reconstruction of Floral Changes During Deposition of the Miocene Embalut Coal from Kutai Basin, Mahakam Delta, East Kalimantan, Indonesia by use of Aromatic Hydrocarbon Composition and Stable Carbon Isotope Ratios of Organic Matter, Organic Geochemistry, 40, 206218.
Downloads
Published
2019-06-18
Issue
Section
Article
License
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons: Attribution-NonCommercial 4.0 International (CC BY-NC) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
Abstract views: 627
,
PDF Downloads: 365
3.png){kind=logo}
